Abstract
The catalytic system “PtBr2(0.3mol%)/2P(OR)3/10nBu4PBr” (R=alkyl) discovered recently in our group, allows good to excellent catalytic activities for the intermolecular hydroamination of ethylene and higher α-olefins (1-hexene) with aniline type amines to give the expected N-ethyl- (1) and N,N-diethyl-anilines (2) along with 2-methyl-quinoline (3). A poisoning effect of alkyl and aromatic phosphines has been observed. This effect could be minimised using small amounts of molecular iodide which reacts with phosphorus ligands to form non-coordinating well-described ionic species. Interestingly, beneficial effects of added P(OR)3 (R=alkyl) have been pointed out and further investigated. In this way, a new potential family of Arbuzov-type phosphorus-metal complexes has been suggested to be responsible for good catalytic activities found when using P(OR)3 alkyl phosphites rather than PR3 (R=alkyl, aromatic) and P(OPh)3 co-catalysts. [Display omitted]
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