Abstract
The surface structure of a Pd layer electrochemically deposited onto Au(111) from PdCl 2− 4 solution has been studied by surface X-ray diffraction. By combining the measurements of the specular and non-specular rod profiles, both in-plane and out-of-plane structures have been determined. On the Au(111) electrode surface, Pd occupies the cubic closest packing site and forms a pseudomorphic smooth monolayer. The formation of the stable Pd overlayer is explained by the lifting of the surface reconstruction of the Au substrate. The PdAu bond length at the Pd/Au(111) interface has been found to be 2.82 Å, which is close to the sum of the atomic radii of Pd and Au in each bulk.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.