Abstract

Vertical copper oxide (CuO) nanoflakes have been formed by oxidation in NaOH solution. Their structural, surface morphology and oxidation states were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and X-ray photoelectron spectroscopy (XPS) respectively. Pseudocapacitive behavior of CuO nanoflakes was investigated by cyclic voltammetry and constant current charge–discharge test. CuO nanoflakes were vertically grown with high lateral aspect ratio and consist of monoclinic lattice as shown by the presence of two peaks close to 2θ=35.6o and 38.7o in the XRD. Charge–discharge test gave a capacitance value of 190Fg−1 in 1.0M KOH electrolyte at 2mAcm−2 current density. The cycling test showed 67% stability after 2000cycles and reduced specific capacitance from 190Fg−1 to 125Fg−1. Specific capacitance of CuO nanoflakes is higher than 26.44Fg−1 of globular CuO at 2mAcm−2 as reported in literature due to enhanced specific surface area.

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