Abstract
Electrocatalytic H + reduction was found with the polynuclear iron-cyanide complex called Prussian White (PW, K 4Fe II 4[Fe II(CN) 6] 3) coated on a Pt electrode. The PW-coated Pt produced much larger amounts of H 2 than a bare electrode even at the theoretical potential of H + H 2 . Its electrocatalytic activity exceeded the conventional Pt catalyst.
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