Abstract
AbstractBinuclear cobalt chelates with O2 as bridging ligand have been prepared, using ethylenediamine, triethylenetetramine, tetraethylenepentamine and tris‐(2‐aminoethyl)‐amine as chelating agents and SCN− and ClO4− as anions. They form well characterized crystals which give off molecular oxygen spontaneously in acid solution and, except in the case of the cobalt tetra‐ethylenepentamine chelate, reveal the general composition [(Z)Co · μ(O2, OH) · Co(Z)]X3, where Z represents the polydentate complexing agents and X the anion. In the presence of ammonia different complexes are produced, in which NH3 occupies one coordination site of each cobalt, replacing the hydroxo bridge.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
