Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3

Alexander S Romanov,Mikhail M Vinogradov,Dmitry V Muratov,Alexander R Kudinov

doi:10.1016/j.mencom.2014.11.016

Protonation of CpFe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [CpFe(MeCN)3

Alexander S Romanov, Mikhail M Vinogradov + Show 2 more

https://doi.org/10.1016/j.mencom.2014.11.016

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Journal: Mendeleev Communications

Publication Date: Nov 1, 2014

Affiliation: A. N. Nesmeyanov Institute of Organoelement Compounds

#Iron Complex Cp #Protonation Of Cp + Show 6 more

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Abstract

The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

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