Abstract
The second moment of the proton nuclear magnetic resonance line and the spin–lattice relaxation time were measured as functions of temperature throughout the trigonal phase of NaSH. Motional narrowing of the resonance line occurs at about 120 K. A T1 minimum was also observed indicating molecular reorientation of the SH− ion. The second moment and the relaxation times were calculated using several models for possible SH− ion motion. The best agreement with experimental results was obtained when the proton was considered to move between two positions either side of the sulfur atom along the trigonal axis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
