Abstract

The two adducts obtained from the Diels-Alder condensation between 1,3-cyclohexadiene and trans-p-Chloro-β-nitrostyrene have been characterized from the PMR spectra of the respective cyclohexane dicarboxylic acids obtained from chromic acid oxidation of the adducts. The Diels-Alder condensation yielded a larger quantity of the isomer with the nitro group endo to the double bond. Hydrogenation of the double bond in the two adducts yielded one product, the PMR spectrum of which is consistent with the expected product. The PMR spectra of the adducts, their oxidation products and the hydrogenation product are reported and discussed.

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