Abstract
Abstract Longitudinal relaxation rates of water protons were determined for aqueous solutions of orthophosphoric acid at concentrations up to 85% by weight, and their concentration dependence was investigated. An appropriate choice of variables yielded an essentially linear plot for concentrations up to at least 15% by weight. Deviations from linearity are discussed and are interpreted in terms of mass-law effects. The use of parameters of this plot for deriving values for correlation coefficients and for a hydration parameter is illustrated by application to observed data and data from the literature.
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