Abstract

AbstractHydronium‐ion batteries have received significant attention owing to the merits of extraordinary sustainability and excellent rate abilities. However, achieving high‐performance hydronium‐ion batteries remains a challenge due to the inferior properties of anode materials in strong acid electrolyte. Herein, a hydronium‐ion battery is constructed which is based on a diquinoxalino [2,3‐a:2’,3’‐c] phenazine (HATN) anode and a MnO2@graphite felt cathode in a hybrid acidic electrolyte. The fast kinetics of hydronium‐ion insertion/extraction into HATN electrode endows the HATN//MnO2@GF battery with enhanced electrochemical performance. This battery exhibits an excellent rate performance (266 mAh g−1 at 0.5 A g−1, 97 mAh g−1 at 50 A g−1), attractive energy density (182.1 Wh kg−1) and power density (31.2 kW kg−1), along with long‐term cycle stability. These results shed light on the development of advanced hydronium‐ion batteries.

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