Abstract
The theoretical description of dynamics in open quantum systems becomes very demanding upon inclusion of non-Markovian effects. To simplify the computational implementation for density matrix equations of motion, the secular approximation is often applied. An experimental verification of its validity though remains difficult due to uncertainties in the system parameters and the absence of qualitatively distinct features. In this paper, we present the proposal for an experimental detection protocol sensitive to nonsecular processes neglected in the secular approximation. The protocol uses a combination of multidimensional coherent spectroscopy and nanoplasmonics. It allows for studies of nonsecular processes in various systems and provides a tool to experimentally verify the validity of the secular approximation. We apply this protocol to a system of CdSe/ZnS nanostructures and discuss the particular features originating from nonsecular processes on the resulting two-dimensional spectra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
