Abstract

AbstractAttempts to rearrange a β‐hydroxy‐alkyne with a secondary hydroxy group into an α,β‐unsaturated ketone failed in the case of a potential prostaglandin intermediate. However, it was possible to convert this intermediate into 13‐hydroxy‐5(Z)‐prosten‐15‐ynoic acids, which are interesting prostaglandin analogues with a modified alkyl side chain.

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