Proposal and thermodynamic investigation of pressurized calcium looping integrated with chemical looping combustion for tail-end CO2 capture in a retrofitted natural gas combined cycle power plant

Abstract

The integration of tail-end calcium looping into an existing natural gas combined cycle (NGCC) power plant has minimal impact on CO2 capture retrofits. However, a high volume of flue gas needs to be preheated before entering the carbonator, and the relatively high energy consumption of oxygen production exacerbates the energy penalty of the NGCC system with tail-end CO2 capture. This paper proposes the method of pressurized calcium looping integrated with chemical looping combustion (PCaL-CLC). It employs the PCaL-CLC method to reduce the energy penalty and energy consumption of the NGCC system with tail-end CO2 capture. Results show that the proposed system using the PCaL-CLC method achieves a 3.0% reduction in energy penalty, decreasing from 9.1% in the reference system employing the calcium looping method to 6.1% in the proposed system. Besides, the specific energy consumption for CO2 avoided (SPECCA) declines from 4.43 MJLHV/kg CO2 to 2.76 MJLHV/kg CO2. Exergy analysis and energy utilization diagrams reveal the underlying reason for improving system performance. Furthermore, by optimizing the operating parameters of the gas turbine and equipping it with advanced heat recovery steam generation, an energy penalty of 2.9% and a SPECCA of 1.21 MJLHV/kg CO2 are achieved without CO2 compression, which is superior to those of amine scrubbing and hot-end CO2 capture technologies. The proposed PCaL-CLC method offers an alternative approach to reducing the energy consumption of tail-end CO2 capture in existing natural gas combined cycle power plants.