Proposal and design of organic/CIGS tandem solar cell: Unveiling optoelectronic approaches for enhanced photovoltaic performance

Abstract

Solar cells are promising devices for converting sunlight into electrical energy. Tandem solar devices, which combine multiple sub cells with complementary absorption spectra, offer a potential strategy to enhance the overall power conversion efficiency (PCE). In this work, the design and performance of organic/CIGS tandem solar devices are investigated. The initial tandem cell comprises two sub cells, namely an organic-based PM6:m-DTC-2 F top cell and CIGS bottom cell. The organic and CIGS cells show a PCE of 12.20% and 20.10%, respectively, where the initial results are based on calibrated cells reproduced from experimental studies. Accordingly, the initial tandem PM6:m-DTC-2 F/CIGS cell shows a PCE of 22.75%. The study focuses on optimizing the PCE via different approaches. Firstly, through the exploration of different hole transport layers (HTLs) of the front cell. Secondly, by investigating the matched current condition between the front and rear cells. Moreover, the doping effect of the CIGS film is investigated. Finally, optimization of the defect concentrations in the absorbers is introduced. These optimizations result in open circuit voltage (Voc) of 1.89 V with short circuit current (Jsc) of 17.55 mA/cm2, and a fill factor (FF) of 82.79%. Consequently, the PCE of the optimized tandem cell is further enhanced to 27.46%. Further, the stability of the proposed tandem cell is evaluated under varying temperatures, and its composition of flexible materials makes it a promising candidate for wearable applications.