Properties, synthesis, and recent advancement in photocatalytic applications of graphdiyne: A review

Abstract

• GDY function as co-catalyst and anchored nanoparticles to enhance the stability. • Basic structure and properties of GDY were elaborated. • The recent development in synthetic methods and different morphology of GDY were considered. • GDY nanocomposites for photodegradation, CO 2 reduction, hydrogen evolution were explored. • Lastly, conclusion and future prospects of research on GDY-based nanomaterials. Carbon materials are inexpensive and high‐performance nanomaterials producing ample scope for versatile applications. Graphdiyne (GDY) is a two-dimensional allotrope of carbon having sp and sp 2 hybridized planar carbon atoms. GDY was firstly synthesized by Li and co-workers in 2010, having diacetylene linkages, conjugated system, wide surface spacing, and pores distribution, tunable electronic properties, good chemical stability, and semiconductor characteristics. In this review, we examine GDY properties, synthesis, bandgap tunability, and current advancement in photocatalytic applications. Recent modifications in electrical, optical, and magnetic properties and some strategies to alter the bandgap of GDY, including applying strain, doping, co-doping, morphology formulation, and heterojunction construction, are elaborated. Different structural and morphological analysis, including nanotube, nanowires, nanosheets, nanowalls, and 3D GDY framework, are also discussed. Earlier GDY studies based on theoretical analysis are being validated by experimentation for feasible photocatalytic applications. The GDY-based nanocomposites were extensively explored for photodegradation, photoreduction of CO 2 , photocatalytic hydrogen production. The focus of this review is to provide an in‐depth understanding of GDY and promote the advancement in the development of next-generation photocatalytic systems derived from carbon materials.