Abstract

The properties of ultra-thin vanadium layers in V/Ru(0001) superlattices grown bymolecular beam epitaxy were studied. The atomic structure of V was investigated byvarious methods including reflection high-energy electron diffraction (RHEED), x-raydiffraction (XRD) and polarized x-ray-absorption fine structure (PXAFS). It appears that,for up to three atomic layers, V adopts a slightly distorted hexagonal-close-packed (hcp)structure induced by pseudomorphic growth on Ru(0001). By increasing the Vthickness to four atomic layers, this structure almost completely relaxes towards thebody-centered-cubic (bcc) bulk structure. This sharp structural transition is alsomanifested in the electronic properties. A reduced superconducting transitiontemperature between 0.6 and 1.05 K was found in the bcc V/hcp Ru superlattice, whilesuperconductivity is quenched in the superlattice with hexagonal V. This behavior mightbe linked to the existence of a ferromagnetic ground state of the metastable V induced bythe hybridization of the d-bands at the hcp V/Ru interface, as predicted fromfirst-principles density-functional theory.

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