Properties of the constant loss in ionically conducting glasses, melts, and crystals

Abstract

A frequency independent or nearly frequency independent contribution to the dielectric loss is present in all ionic conductors independent of the chemical and physical structures. An exhaustive collection of dielectric relaxation data of glassy, crystalline, and molten ionic conductors are analyzed to obtain the magnitudes of their constant losses and the dependencies on temperature, ion density, ion mass, dc conductivity activation energy, dc conductivity level, the nonexponential conductivity relaxation parameter β, the mixed alkali effect, and the decoupling index Rτ. Trends of changes in the constant loss when modifying the structure of the glassy matrix or mixing two different alkali ions are also found. In a glass-forming molten salt, 0.4Ca(NO3)2⋅0.6KNO3, the constant loss turns out to have approximately the same temperature dependence as the mean square displacement of the ions obtained by elastic neutron scattering measurement. All dependencies and properties found indicate that the physical origin of the constant loss may be traced to the displacement of the ions in their local librational or vibrational motion, but anharmonicity is not a necessary ingredient.