Abstract

In this work, silicon-rich silicon nitride (SRN) layers were deposited on a silicon wafer bymicrowave-assisted plasma-enhanced chemical vapor deposition (MW-PECVD) usingNH3 andSiH4 as precursor gases. The Si excess in the as-deposited layers as determined by theRutherford backscattering technique was controlled by varying the precursor gasratio. We were able to produce silicon nanoparticles (Si-nps) in the silicon nitride (SiNx) layers upon thermal annealing at high temperature. Energy-filtered TEM (EFTEM),complemented by photoluminescence measurements, were used to identify the experimentalparameters in order to reach a high density of well-separated Si-nps (3 nm). Our resultsshow that the MW-PECVD method is a suitable deposition tool for the formation of Si-npsin thin SRN layers.

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