Abstract
AbstractHydroxy‐terminated copoly(fstyrene‐b‐1,2‐butadiene) (HPSB) containing rubber‐affinitive vinyl side chains and having a molecular weight of 2000 to 4000 were prepared, and block copolyurethanes were synthesized by using a low molecular weight hydroxy‐terminated poly (ethyl en e terephthalate) as a PET‐affinitive component and 4,4′‐diphenylmethane diisocyanate as a chain extender. The relationships between the molecular weight of HPSB, copolymerization ratio of styrene to butadiene and the adhesive strength of PKT/rubber in high temperature atmospheres were examined. A peak of adhesive strength was observed at styrene copolymerization ratio of 20 wt percent and a HPSB molecular weight of 3000. The adhesion mechanism was estimated from the behavior of the characteristic infrared absorption of block Copolyurethane in heating.
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