Abstract

(Nb 1 − xTa x) 2O 5 solid solution films and (Nb 1 − xTa x) 2O 5-ZrO 2 nanolaminates have been deposited by Atomic Layer Epitaxy. Amorphous (Nb 1 − xTa x) 2O 5 films were obtained by sequential pulsing of tantalum and niobium ethoxide and water. The composition of the films was checked by Energy Dispersive X-ray Spectroscopy. (Nb 1 − xTa x) 2O 5 films exhibited 1.6–4 times higher permittivity than that of Ta 2O 5 films. Leakage currents through the (Nb 1 − xTa x) 2O 5 films were reduced drastically by adding intermediate ZrO 2 layers with thickness of 5–10 nm i.e. by constructing nanolaminate structures. The ZrO 2 interlayers contained nanosize tetragonal ZrO 2 crystallites.

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