Properties of Glass-Ceramics Prepared from Industrial Multi-Wastes

Abstract

Because of their excellent properties, glass-ceramics have been widely developed and applied in many fields, and there are many potential application values to be disseminated. The preparation of glass-ceramics from industrial slag and metallurgical waste provides a new way for the comprehensive utilization of solid waste. Coal gangue is the largest of all kinds of industrial waste slag, while iron tailings and high-carbon ferrochrome slag also occupy a large proportion of China’s industrial solid waste. With cheap industrial solid waste as the main raw material, the production of high-value-added glass-ceramics can reduce pollution, protect the ecological environment, and have good economic and social benefits. Cordierite glass-ceramics were prepared using the sintering method with coal gangue, iron tailings, and high-carbon ferrochrome slag as the main raw materials. Meanwhile, an iron silicon alloy containing chromium was obtained. The heat treatment system of basic glass was determined by differential scanning calorimetry (DSC), and the sintered product was analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). An orthogonal test was used to analyze the effects of the mass of basic glass powder, molding pressure, and holding time on the grain size and crystallinity of the samples. The hardness, acid and alkali resistance, density, and water absorption of the sintered products were determined. The results show that the main crystal phase of the prepared glass-ceramics is cordierite. The optimal combination for the green body is “basic glass powder mass 6 g, molding pressure 35 MPa, holding time 10 min”. The properties of glass-ceramics are good. At the crystallization temperature of 970 °C, the Vickers hardness is up to 866 HV, and the bulk density is up to 2.99 g/cm3. This study may provide a useful reference for the treatment of industrial solid waste.