Abstract

The induction of electronic motion by nuclear motion is described for the particular case of the absorption of infrared radiation by chiral molecular systems. The description is in terms of an effective vector potential, which is obtained by averaging over the electronic coordinates. This effective vector potential can be visualized in a number of ways. Nine of these are tabulated and discussed. Strong evidence is presented that the interaction of rings with radiation can be treated in the same way as the interaction with chains. Evidence is also obtained that the bulk of the induced electronic motion can be determined semiclassically.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.