Properties of composite oxide layers on the Ti13Nb13Zr alloy

Abstract

ABSTRACTThe development of composite oxide layers on the Ti13Nb13Zr alloy, their structure and properties, were demonstrated. Two subsequent methods were applied to prepare the composite layers. During the first stage, gas oxidation produced a dense compact oxide layer, and subsequent oxide nanotubes were formed applied an electrochemical oxidation. The scanning electron microscopy, energy-dispersive X-ray spectroscopy, electrochemical impedance spectroscopy, and Raman spectroscopy were used to examine the appearance, thickness, chemical and phase composition of the oxide layers. The results obtained revealed that the composite layers composed of two zones. The electrochemical formation of the outer nanotubular oxide zone occurred if the thickness of the first inner oxide zone was small enough because of resistance increasing with the inner zone thickness followed by a decrease in electrochemical reaction rate. The decreasing corrosion resistance of the Ti13Nb13Zr alloy was observed and explained by a model electric circuit.