Properties and structural coloured film preparation of some chiral dopants derived from D-Isosorbide

Abstract

A series of chiral dopants derived from D-isosorbide were synthesized. Some of them exhibita monotropicsmecticA phase. Comparison of the melting points of these chiral dopants, the decrease of them is mainly driven by the large entropy change. The helical twisting power (HTP) values of these chiral dopants with branched alkyl chains, lateral fluoro-substituents and double bonds are lower than those of the chiral dopants with hexyloxy chains. Structural colored polymer films with a right-handed helix are prepared using these chiral dopants.