Abstract
3-Thia[3.2.2]propellane has been synthesized. The Stevens rearrangement was executed for a number of model compounds in the hope that a thiacyclopentane sulfonium salt would be converted into a substituted cyclobutane ring. The reaction took the course of ring-opening to compounds containing exomethylene groups. Thus the synthesis of [2.2.2]propellane by this route failed.
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