Propane oxidation in a Jet Stirred Flow Reactor. The effect of H2O as diluent species

Abstract

Advanced combustion technologies, such as MILD, LTC (Low Temperature Combustion) reduce emission of pollutants by controlling system working temperatures to values not critical to promote the formation of several classes of pollutants. To access this temperature range, a significant dilution of reactants is required. At the same time, reactants have to be preheated to sustain the oxidation process. Such conditions are achieved by a strong recirculation of exhaust gases. Such a strategy implies that high contents of CO2 and H2O interact with reactants oxidation chemistry. In order to characterize this aspect of the combustion processes under diluted conditions, experimental tests were carried out for propane/oxygen/nitrogen mixtures in presence of variable amounts of H2O in a quartz Jet Stirred Flow Reactor (JSFR). Experiments were carried out at atmospheric pressure, over the temperature range 720–1100 K, from fuel lean to rich conditions and at a residence time of 0.5 s. Temperature and species concentration measurements suggest that the oxidation of propane is significantly altered by H2O in dependence of mixture inlet temperatures and equivalence ratios.Numerical analyses were performed to explore the interaction of H2O with the oxidation chemistry of propane. Results suggested that such a species alters the main radical branching mechanisms, i.e. in termolecular reactions as a third body species with high collisional efficiency or directly participating in bimolecular reactions.