Abstract

The flammable propane–air mixtures raise specific safety and environmental issues in the industry, storage, handling and transportation; therefore dilution of such mixtures has gained significant importance from the viewpoint of fire safety, but also due to nitrogen oxide’s emission control through flameless/mild combustion. In this paper, the propagation of the flame in C3H8-air-diluent stoichiometric gaseous mixtures using Ar, N2 and CO2 as diluents was investigated. Data were collected from dynamic pressure-time records in spherical propagating explosions, centrally ignited. The experiments were done on stoichiometric C3H8-air + 10% diluent mixtures, at initial pressures within 0.5–2.0 bar and initial temperatures within 300–423 K. The flame velocity was determined from laminar burning velocities obtained using the pressure increase in the incipient stage of flame propagation (when the pressure increase is lower than the initial pressure). The experimental propagation velocities were compared with computed ones obtained from laminar burning velocities delivered by kinetic modeling made using the GRI mechanism (version 3.0) with 1D COSILAB package. The thermal and baric coefficients of propagation velocity variation against the initial temperature and pressure are reported and discussed.

Highlights

  • IntroductionThe laminar burning velocity (abbreviated further as LBV or Su ) and the propagation velocity of flames (abbreviated further as PV or Ss ) are important parameters of flammable mixtures

  • The PV has a primordial role for assessing risk factors in operating chemical reactors with flammable mixtures, for design of safety devices or explosion vessels [3,4]

  • It is observed that for the studied ranges of initial pressure p0 : 0.5–2 bar and initial temperature T0 : 300–423 K, the propagation velocities of propane-air-inert flames strongly depend on initial pressure and temperature of flammable mixtures

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Summary

Introduction

The laminar burning velocity (abbreviated further as LBV or Su ) and the propagation velocity of flames (abbreviated further as PV or Ss ) are important parameters of flammable mixtures. These parameters are significant for the heat generation rates and rates of fuel conversion to oxidation products. The PV (propagation velocity or “flame speed”), was defined as the velocity of the flame front in respect to the vessel where combustion takes place [2,3]. The PV is an important parameter in the design of burners and gas turbines, for predicting the flame flash-back, blow-off, and the dynamic flame instabilities. The PV has a primordial role for assessing risk factors in operating chemical reactors with flammable mixtures, for design of safety devices or explosion vessels [3,4]

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