Abstract
Small amount of Pt, Pd and Ru promoters in Co/SiO 2 led to great improvement of catalyst activity for hydroformylation of 1-hexene. The 1-hexene conversion as high as 89.7% and oxygenate products selectivity of 88.9% were obtained after 2 h reaction over Pd promoted Co/SiO 2 catalyst. The increasing of reduction degree, the minimizing of cobalt particle size and the enhancement of carbonyl and linear CO adsorption were responsible for the improved performance of the catalyst.
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