Abstract
Two new results emerging from inner-shell photodetachment of transition metal negative ions are obtained, following studies in Pt−. First, the d-wave form of the Wigner threshold law is observed for the first time in single-photon measurements. Second, single-vacancy valence shells are filled with a core electron. While this should result in stabilization of the core excited state, producing Feshbach resonances, we find that stabilization does not occur for some core excitations, dramatically demonstrating the importance of core-valence interactions.
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