Abstract

Immersion experiments have been performed to investigate the progressive dissolution of 0.3-mm-thick foils of molybdenum metal in liquid uranium at 1160 ° C, for immersion times of 3, 6, 10, and 60 min, and 20 h, in a zarconia crucible. The original foils, as-received and heat-treated at 1160 ° C, and the uranium-reacted foils have been studied microscopically (SEM-EDAX) and the internal morphology has been determined. The flow lines in as-received molybdenum disappear under heat-treatment, while the undistinguishable grains recrystallize upon heating into grains with average size of 20 μm, persisting in samples immersed in liquid uranium. The recrystallization is not uranium-assisted, as uranium does not penetrate into intergranular regions. After incubation time of 3–4 min, outer molybdenum grains dissolve in liquid uranium, thereby reducing the foil thickness progressively. Full dissolution occurs for about 15-min immersion.

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