Progress of Reactions between Furfural and Aliphatic Alcohols via Catalytic Oxidation Processes: Reaction Routes, Catalysts, and Perspectives

Abstract

Furfural is one of the most important biomass platform compounds and can be used to prepare various high-value-added chemicals. The reactions of furfural with aliphatic alcohols via an oxidative esterification reaction or oxidative condensation reaction can bond two carbon molecules together and produce longer hydrocarbon chains chemicals, including methylfuroate and some low-volatility liquid biomass fuels. Thus, these reactions are considered significant utilization routes of furfural, and many inspiring catalytic systems have been designed to promoted these reactions. In this work, the reported catalytic systems for the oxidative esterification and oxidative condensation reactions are reviewed separately. The catalysts for the oxidative esterification reaction are reviewed for the classification of noble metal catalysts and non-noble metal catalysts, according to the active metals in the catalysts. For the oxidative condensation reactions, the studies using oxygen as the oxidant are reviewed firstly, and then the studies conducted using the hydrogen transfer process are analyzed subsequently. Furthermore, suggestions for future research directions for the oxidative esterification and oxidative condensation reactions are put forward.