Progress of 2D MXene as an Electrode Architecture for Advanced Supercapacitors: A Comprehensive Review.

Abstract

Supercapacitors, designed to store more energy and be proficient in accumulating more energy than conventional batteries with numerous charge-discharge cycles, have been developed in response to the growing demand for energy. Transition metal carbides/nitrides called MXenes have been the focus of researchers' cutting-edge research in energy storage. The 2D-layered MXenes are a hopeful contender for the electrode material due to their unique properties, such as high conductivity, hydrophilicity, tunable surface functional groups, better mechanical properties, and outstanding electrochemical performance. This newly developed pseudocapacitive substance benefits electrochemical energy storage because it is rich in interlayer ion diffusion pathways and ion storage sites. Making MXene involves etching the MAX phase precursor with suitable etchants, but different etching methods have distinct effects on the morphology and electrochemical properties. It is an overview of the recent progress of MXene and its structure, synthesis, and unique properties. There is a strong emphasis on the effects of shape, size, electrode design, electrolyte behavior, and other variables on the charge storage mechanism and electrochemical performance of MXene-based supercapacitors. The electrochemical application of MXene and the remarkable research achievements in MXene-based composites are an intense focus. Finally, in light of further research and potential applications, the challenges and future perspectives that MXenes face and the prospects that MXenes present have been highlighted.