Abstract

The anodization of aluminum is an electro-chemical process that changes the surface chemistry of the metal, via oxidation, to produce an anodic oxide layer. During this process a self organized, highly ordered array of cylindrical shaped pores can be produced with controllable pore diameters, periodicity and density distribution. This enables anodic aluminum oxide (AAO) membranes to be used as templates in a variety of nanotechnology applications without the need for expensive lithographical techniques. This review article is an overview of the current state of research on AAO membranes and the various applications of nanotechnology that use them in the manufacture of nano-materials and devices or incorporate them into specific applications such as biological/chemical sensors, nano-electronic devices, filter membranes and medical scaffolds for tissue engineering.

Highlights

  • The anodization process of metals has been used by industry to protect metal components from corrosion for approximately 90 years

  • Nanotechnology research to a large extent is focused on the controlled fabrication of functional nano-scale structures and devices

  • Aluminum metal (Al) anodization is a relatively inexpensive electro-chemical and controllable process that allows the self-assembly process to dictate the development of porosity, mechanical properties and morphology of the anodic aluminum oxide (AAO) membrane

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Summary

Introduction

Nanotechnology research to a large extent is focused on the controlled fabrication of functional nano-scale structures and devices. One of the most important aspects of self-assembly lies in the capability of producing uniform structures over a large area using inexpensive chemical or biological processes. Al anodization is a relatively inexpensive electro-chemical and controllable process that allows the self-assembly process to dictate the development of porosity, mechanical properties and morphology of the AAO membrane. These membranes with their cylindrical pore geometry can be used as a template for the fabrication of nanostructures and nano-scale devices. While Martin et al has discussed the application of AAO membranes in molecular filters [111]

Types of Oxide Films on Aluminum
AAO Electrochemistry
Materials
Electrolytes
Non Acids and Neutral Solutions
Voltage Conditions
Barrier Layer Formation
Nano-Porous Alumina Formation
Two-Step Anodization of Aluminum
A Typical AAO Membrane Fabrication Technique
Engineering Applications of AAO Layers
Electronic and Photoluminescence Properties of AAO Membranes
Nano-Dots and Nano-Magnets
Biological Applications
Concluding Remarks
Findings
Disclosure
Full Text
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