Abstract
Abstract Copper-catalyzed Ullmann-type coupling reactions have become an important powerful synthetic method in modern organic synthesis. Compared with the usually used organic solvent, employing abundant, cheap, environmental-friendly water as reaction media is obviously more fitful for green chemistry and low carbon sustainable development. The recent progress of copper-catalyzed Ullmann-type including C—N, C—O, C—S and C—C coupling reactions by using water as solvent is reviewed.
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