Prograde mica 40Ar/ 39Ar growth ages recorded in high pressure rocks (Syros, Cyclades, Greece)

Abstract

Phengites from the eclogite and blueschist-facies sequences of the Cycladic island of Syros (Greece) have been dated by the in situ UV-laser ablation 40Ar/ 39Ar method. A massive, phengite-rich eclogite and an omphacite-rich metagabbro were investigated. The phengites are euhedral and coarse-grained (several 100 μm), strain-free and exhibit no evidence for late brittle deformation or recrystallization. Apparent ages in these samples range from 43 to 50 Ma for the phengite-rich eclogite and 42 to 52 Ma for the omphacitic metagabbro. This large spread of ages is visible at all scales—within individual grains as well as in domains of several 100 μm and across the entire sample (ca. 2 cm). Such variations have been traditionally attributed to metamorphic cooling or the incorporation of excess argon. However, the textural equilibrium between the phengites and other high pressure phases and the subtle compositional variations within the phengites, especially the preservation of growth textures, alternatively suggest that the observed range in ages may reflect variations of radiogenic argon acquired during phengite formation and subsequent growth, thus dating a discrete event on the prograde path. This implies that the oldest phengite 40Ar/ 39Ar ages provide the best estimate of a minimum crystallization age, which is in agreement with recently reported U–Pb and Lu–Hf geochronological data. Our results are consistent with available stable isotope data and further suggest that, under fluid-restricted conditions, both stable and radiogenic isotopic systems can survive without significant isotopic exchange during subduction and exhumation from eclogite–facies P– T conditions.