Profile of particulate-bound organic compounds in ambient environment of Srinagar: a high-altitude urban location in the North-Western Himalayas.

Abstract

Twenty-four hourly samples of total suspended particulate matter (TSPM) were collected once a week over 17months in the ambient environment of Srinagar (altitude 1524m), an urban montane location in the North-Western Himalayas. The samples were analyzed to identify and quantify the presence of diverse organic compounds (OCs) using thermal desorption gas chromatography mass spectroscopy (TD-GCMS). Non-polar organic compounds-n-alkanes, polycyclic aromatic hydrocarbons (PAHs), and molecular tracers (retene and nicotine), were detected in the TSPM samples. Molecular diagnostic ratios, derived from the quantified n-alkanes and PAHs in TSPM, assisted in characterization of the contributing sources. Significant variation in the planetary boundary layer height (meters) with change in season (summer to winter) in this region, also, affected the observed variation in the temporal profile of TSPM-bound OCs. TSPM-bound OCs were predominantly contributed from petroleum and biomass combustion; to a lesser extent from biogenic sources. High concentrations of retene and nicotine, known molecular tracers for coniferous wood combustion and tobacco smoke, respectively, were detected in the winter samples. Seasonal variation in TSPM-bound retene corresponded with the periodicity of biomass burning activity in the region. The benzo(a)pyrene equivalent (BAPE) concentrations, a measure for the carcinogenicity of TSPM-bound PAHs was calculated and the value exceeded the prescribed international standards in winter. This finding poses a major health concern for the inhabitants of this region. High BAPE concentration of PAHs during winter was linked to fossil fuel and biomass combustion, where the prevalent meteorology and topography played a synergistic role.