Products of the quenching of NO A 2Σ+ (v = 0) by N2O and CO2

Abstract

Collisional quenching of NO A (2)Σ(+) (v = 0) by N(2)O and CO(2) has been studied through measurements of vibrationally excited products by time resolved Fourier transform infrared emission. In both cases vibrationally excited NO X (2)Π (v) is seen and quantified in levels v≥ 2 with distributions which are close to statistical. However the quantum yields to produce these levels are markedly different for the two quenchers. For CO(2) such quenching accounts for only ca. 26% of the total: for N(2)O it is ca. 85%. Far more energy is seen in the internal modes of the CO(2) product than those of N(2)O. The results are rationalised in terms of cleavage of the N(2)-O bond being dominant in the latter case, with either a similar O atom production or a specific channel producing almost exclusively NO in low vibrational levels (v = 0,1) for quenching by CO(2). Minor reactive channels yielding NO(2) are seen in both cases, and O((1)D) is observed with low quantum yield in the reaction with N(2)O. The results are discussed in terms of previous models of the quenching processes, and are consistent with the very high yield of NO X (2)Π (v = 0) previously observed by laser induced fluorescence for quenching of NO A (2)Σ(+) (v = 0) by CO(2).