Abstract

The vibration-rotation bands (Meinel bands) of the ground electronic state of OH have been observed in the chemiluminescent gas phase reactions of ozone with ethylene, propylene, 1-butene, cis-2-butene and tetramethylethylene at total pressures of about 3 torr at room temperature. The emitting species in the reactions of the 1-olefins with ozone have been tentatively identified as HCHO( 1A 2) and electronically excited α-dicarbonyl compounds.

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