Production of vaterite via wet carbonation of carbide residue: Enhancing cement properties and CO2 sequestration

Abstract

The influence of limestone powder (primarily composed of calcite) on hydration and properties of concrete has been extensively researched. However, there is limited understanding of how different calcium carbonate (CC) polymorphs affect cement hydration due to the difficulty in formation of vaterite. Therefore, preparing calcite and vaterite from solid waste carbide residue (CS) by wet carbonation and examining influence of these two CC polymorphs (0–20 %) on cement hydration and properties are comprehensive investigated in the paper. The results reveal that pure cubic calcite can be obtained through CS carbonation, while high-purity spherical vaterite can be synthesized using glycine as a regulator. The specific surface area (SSA) of spherical vaterite (15.47 m2/g) is approximately three times that of calcite (4.8 m2/g) with a comparable particle size distribution (PSD). The addition of calcite reduces the flowability of cement, whereas vaterite enhances it. The cement mortar with calcite demonstrates a lower compressive strength, while the incorporation of vaterite results in a higher or comparable compressive strength in contrast to control sample. Compared with control cement hydration, new hydration products, like monocarbonate aluminate and hemicarbonate aluminate, are formed with the addition of both calcite and vaterite. The metastable vaterite exhibits increased reactivity. The research presents a novel approach for the valorisation of solid wastes through CO2 sequestration, offering insights into the preparation of highly added-value products.