Production of pyrolytic lignin for the phenolic resin synthesis via fast pyrolysis

Abstract

Recycling of waste wood into resol type phenol-formaldehyde (PF) resins via fast pyrolysis was demonstrated. Waste wood collected from the building demolition site in Finland was pyrolyzed with 20 kg/h circulating fluidized bed pyrolysis pilot unit. Pilot was operated with high organic liquid yield (60 wt% on average) and the produced fast pyrolysis bio-oil was fractionated by water addition into aqueous phase and water insoluble phase. The obtained fractions were characterized, and the water-insoluble viscous lignin fraction was used in the synthesis of PF-resins. Commercial phenol was successfully replaced by pyrolytic lignin fraction at 10 wt%, 20 wt%, 30 wt%, 40 wt% and 50 wt% producing resins of low in free formaldehyde content, but resins with high replacement ratio exhibited higher viscosities. The use of H2O/n-butanol mixture as solvent at a ratio 70:30 wt/wt% proved capable to prolong the storage time of the resin and helped to maintain the viscosity at acceptable values for at least 2 weeks before their use in the targeted application. Finally, the gluing performance of the resins was evaluated by measuring the tensile shear strength of lap joints formed by gluing 5 mm thick beech wood veneers. All the produced resins fulfilled a dry strength limit of ≥ 10 N/mm2. Wet strength limit ≥ 7 N/mm2 was fulfilled by the resins with the replacement ratio up 40 wt%, but resins with replacement ratio of 50 wt% had somewhat reduced wet strength. These results confirm a promising protentional application of pyrolysis derived lignin fraction in phenolic wood adhesives, at least in dry conditions.