Abstract
Stationary afterglow techniques have been employed to determine reaction rate constants for ions reacting in NO–H2O gas mixtures. Krypton resonance radiation at 123.6 and 116.5 nm is used to ionize only the NO molecules. The NO+ ion is the precursor to a chain of reactions which result in NO+·nNO(n = 1,2), NO+·nH2O(n = 1,2,3), and H3O+·nH2O(n = 2,3,4) being formed. Rate constants and/or equilibrium constants are provided for all forward and all reverse reactions at 296°K.
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