Abstract

Kr clusters produced in a supersonic nozzle expansion have been studied by electron impact ionization mass spectrometry. Mass resolved spectra (with n up to 180) show two homologous series consisting of Kr+n and Kr2+n ions. The distribution of Kr+n ions shows distinct magic number effects, the observed abundance anomalies being very similar to the ones observed in Ar and Xe. This confirms the superior stability of closed-shell and -subshell icosahedral structures. Moreover, we have found evidence for the occurrence of Kr3+n and Kr4+n ions. It was possible to determine appearance sizes of these multiply charged cluster ions (yielding n2=69, n3=156, and n4=264), and to study the electron energy dependence of singly and doubly charged cluster ions (yielding a linear threshold law). These results are discussed in view of various theoretical considerations and previous results where available.

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