Abstract

Bulk metallic glass matrix composites (BMGMC) are unique materials of future having excellent mechanical properties (such as high hardness, strength and profound elastic strain limit). However, they exhibit poor ductility and suffer from catastrophic failure on the application of force. The reasons behind this are still not very well understood. In this study, an effort has been made to overcome this pitfall by solidification processing. Zr based BMGMCs are produced in the form of “as cast” wedges using vacuum arc melting and suction casting button furnace. The idea is to study the effect of cooling rate and inoculation on formability during solidification. Adjustment, manipulation and proper control of processing parameters are observed to reflect upon the quality of ingots such as improved castability, proper mold filling and defect free casting as characterized by NDT. Further, thermal analysis, optical microscopy and hardness measurement confirmed the formation and evolution of in-situcomposite structure. This is first footprint of pathway towards sustainable manufacturing of these alloys in future.

Highlights

  • Zr based Bulk metallic glass matrix composites (BMGMC) are produced in the form of “as cast” wedges using vacuum arc melting and suction casting button furnace

  • Bulk metallic glass matrix composites have attracted the attention of scientific community lately due to their unique and superior mechanical properties which include high hardness, associated high strength and very high elastic strain limit which make them suitable for applications which require shook energy absorp

  • Various techniques have been proposed to achieve this such as powder processing [48] [49], fluxing [50] [51] [52], solid state processing [53], semi-solid processing [54], twin roll casting (TRC) [55] [56], thermoplastic forming (TPF) [57] [58], blow molding/forming [59] [60] and superplastic forming [61] which may serve the purpose of producing strong and tough material [62] [63] [64] but vacuum arc melting (VAM) and suction casting remains as the major method for most of production of these alloys in the world

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Summary

Introduction

Various techniques have been proposed to achieve this such as powder processing [48] [49], fluxing [50] [51] [52], solid state processing [53], semi-solid processing [54], twin roll casting (TRC) [55] [56], thermoplastic forming (TPF) [57] [58], blow molding/forming [59] [60] and superplastic forming [61] which may serve the purpose of producing strong and tough material [62] [63] [64] but vacuum arc melting (VAM) and suction casting remains as the major method for most of production of these alloys in the world It relies on melting a certain precursor of alloying elements in vacuum arc melting (VRM) furnace and drawing molten melt in a water cooled Cu mold (length/diameter > 1) under the action of pressure difference causing a suction effect producing rod shape specimens. Various efforts covering both theoretical (modeling and simulation) and experimental fronts have been made to understand and describe the nucleation and growth pheno-

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