Abstract
The product channels for the NF(a 1Δ)+CO quenching reaction, either chemical reaction with formation of NCO+F or physical quenching with formation of NF(X 3Σ −)+CO, have been studied in a flow reactor at 300 K. Laser-induced fluorescence measurements of the NCO concentration show that the spin-conserving chemical reaction is the main pathway. The yield of NCO was calibrated from the stoichiometric F+HNCO reaction giving HF+NCO.
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