Abstract
Poly(hydroxyethyl methacrylate/ethylene glycol dimethacrylate) [poly(HEMA/ EGDMA)]-Procion Red MX-3B microspheres were used for removal of Cd(II) ions from aqueous solutions containing different amounts of Cd(II) ions (5–60 ppm). Dye-derived microbeads carrying 8.95 μmol Procion Red MX-3B/g polymer were used in the adsorption-desorption of Cd(II) ions. High adsorption rates were observed at the beginning of adsorption and then equilibrium was achieved in about 5–10 min. The maximum adsorption of Cd(II) ions onto the Procion Red MX-3B-derived microspheres (i.e., by chelate formation of Cd(II) ions with dye molecules) was about 4.2 mg Cd(II) ions/g polymer, which was observed at pH 7.0. While non-specific adsorption onto the underived microspheres was 0.93 mg Cd(II) ions/g polymer. More than 96% of the adsorbed Cd(II) ions was desorbed in 15 min by using 0.1 M HNO3 as an desorption agent. The regenerability of the dye-derived microspheres was also sufficient.
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