Processing, properties and morphology of polypropylene‐epdm blends

Abstract

AbstractBlends of polypropylene and an elastomer (ethylene propylene diene terpolymer, EPDM) are systematically investigated to determine the effect of the rubber on the polymer properties. Five compositions on the complete range of blend compositions are analyzed. The study reported here is a first of a series which main objective is to analyze in a systematic way the influence of the different factors that determine the effectiveness of EPDM as an impact modifier for PP. In this first part of the study, the processing behavior of the PP‐EPDM blends are analyzed and the mechanical properties of the processed blends (tensile, flexural and impact resistance) are examined. Halpin‐Tsai and porosity models successfully represent the mechanical behavior of the blends. The model results allow a physical interpretation of the role of the dispersed phase in terms of the aspect ratio and of the stress concentration factors associated to the dispersed particles. Moreover, the mechanical properties are correlated with the morphology of the blends studied by scanning electron microscopy, where two phases are clearly observed in the complete range of compositions. The results show that PP‐EPDM blends with at low rubber content present a good processability, without significant deterioration with respect to neat PP and with a considerable improvement of the room and low temperature performance.