Abstract

During anaerobic digestion (AD) process, process parameters e.g., VFA, pH, COD removal … and kinetic parameters e.g., hydrolysis rate, lag phase and methane production potential… are the important indicator for illustrating AD process performance, however, the AD process performance based on these parameters remains poorly understood. To estimate process performance focusing on initial pH and substrate composition, the effects of initial pH and swine manure to corn straw ratio on biogas production and these parameters and linkages of these parameters were analyzed. Also, the methane production was optimized. The results revealed that the maximum methane yield and methane production rate were obtained with initial pH 7.5 and SM/CS ratio of 70:30. Kinetic parameters are coupled with process parameters, especially for COD removal rate, VS degradation rate, VFA and pH. Hydrolysis constant positively correlated with pH, COD removal rate and VS degradation rate, then impacted methane production and lag phase. Meanwhile, lag phase and the maximum methane production rate were directly determined by VFA and COD removal rate. The optimum initial pH and SM/CS ratio were 7.15 and 0.62, respectively, with a predicted maximum methane content of 55.12%. Thinking these findings together, they provide a scientific theory for estimating AD performance.

Highlights

  • Anaerobic co-digestion has been regarded as one of the more promising options for increasing biogas production because of its better nutrient balance and improved efficiency

  • (1) The accumulative methane production increased with increase in the swine manure to crop straw (SM/CS) ratio

  • The result obtained for T-group (220 mL g−1 of volatile solids: VS) was significantly higher than for R and T-group, respectively (P < 0.05)

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Summary

Introduction

Anaerobic co-digestion has been regarded as one of the more promising options for increasing biogas production because of its better nutrient balance and improved efficiency It has been extensively applied as an effective waste management and energy production treatment[1, 2]. During the AD process, alkalinity is a better indicator of process performance and directly shows the system’s buffering capacity This can be managed by adjusting pH value; pH adjustment could provide a way to improve the self-buffering capacity of AD systems to meet the requirements of the microbial populations[6]. Much less attention has been given to investigation of the AD performance by analyzing how substrate characteristics and environmental conditions are related to process and kinetic parameters, to understand well the effects of operational conditions on methane production.

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