Process limitation for p-type CuSbS2 semiconductor with high electrical mobility of 20 cm2 V−1 s−1

Abstract

CuSbS2 bulks have been prepared by reactive sintering the mixture of CuS and Sb2S3 at 350, 375, 400, 450, and 500°C for 2h and at the sintering temperature of 400°C for 0.5, 1, 2, and 3h under a compensation disc of CuS for atmospheric control. Composition, Structure, morphology, and electrical properties of the sintered bulks were analyzed. The compositions of Cu, Sb and S did not change until the temperature reached at and above 450°C. The highest electrical conductivity of 15Scm−1 and the highest mobility of 20cm2V−1s−1 were achieved for CuSbS2 sintered at 400°C for 2h. 5% deviations in the Cu/Sb and S/(Cu+Sb) rations caused a serious problem in the degradation of electrical properties, though the CuSbS2 remained as a single phase. Therefore, CuSbS2 is the semiconductor needs to have a controlled composition.