Abstract

The entry region vane turbulence promoters are inserted at the downstream of a circular electrolytic cell and limiting current data are measured at the copper micro electrodes fixed on an electrode support. The effect of flow rate of the electrolyte, effect of velocity on mass transfer at the wall, effects of geometric parameters diameter of the vane (dv) from 0.02 m to 0.04 m, the angle of the vane (γ) from 15° to 60°, sectorial angle (α)/number of the vanes (N) from 4 to 8, diameter of the annular rod of mass transfer is investigated. The electrolyte was equimolal potassium ferricyanide, potassium ferrocyanide and excess sodium hydroxide. Limiting current data had been obtained for the reduction of potassium ferricyanide ion. The mass transfer correlation is based on the law of the wall similarity. The effect of each parameter was studied in terms of friction factor. A model was developed for mass transfer. The correlation may be extended to a wider range of parameters by virtue of the law of the wall. The experimental data on mass transfer was modelled in terms of mass transfer function and Reynolds number geometric parameters.

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