Probing the Interaction Mechanism between Oil-in-Water Emulsions and Electroless Nickel–Phosphorus Coating with Implications for Antifouling in Oil Production

Abstract

Fouling issues are highly undesirable in oil industries, and stable water–oil emulsion is one of the major causes of fouling on pipelines, upgrading equipment, and other surfaces in oil production. Studying the interfacial interactions between emulsion drops and various metal substrates is of significant importance in the fundamental understanding of fouling mechanisms. In this work, surface force measurements using a drop probe atomic force microscope technique and fouling tests were applied to investigate the fouling and antifouling mechanisms of electron-beam-deposited iron substrates with and without electroless nickel–phosphorus (EN) coatings. The effects of oil or aqueous solution conditions have been systematically investigated, including the asphaltene concentration, salinity, pH, and presence of divalent ions. A theoretical model based on the Reynolds lubrication equation and augmented Young–Laplace equation has been applied to analyze the measured force profiles. Our results indicate that the at...